Ultra High MolecularWeight Polyethylene

UHMWPE

8/30/2008

Ultra high molecular weight polyethylene (UHMWPE), also known as high-modulus polyethylene (HMPE) or high-performance polyethylene (HPPE), is a subset of the thermoplastics polyethylene.  It has extremely long chains, with molecular weight umbering in the millions, usually between 2 and 6 million. The longer chain serves to transfer load more effectively to the polymer backbone by strengthening intermolecular interactions. This results in a very tough material, with the highest impact strength of any thermoplastic presently made. It is highly resistant to corrosive chemicals, with exception of oxidizing acids. It has extremely low moisture absorption, has a very low coefficient of friction, is self-lubricating, and is highly resistant to abrasion abrasion (15 times more resistant to abrasion than carbon steel). Its coefficient of friction is significantly lower than that of nylon and  acetal, and is comparable to that of Teflon, but UHMWPE has better abrasion resistance than Teflon. It is odorless, tasteless, and nontoxic.”
Wikipedia: http://en.wikipedia.org/wiki/Dyneema (11/3/2008)

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UHMWPE Degradation

UHMWPE Applications

Warning:  Sometimes the older links no longer work.  Go to the US Patent Patent number search page, copy the Patent number into the search box and search.  For the articles, use your browser to go the Journal site. 

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“Polymerisation of UHMWPE was commercialised in the 1950s by Ruhrchemie AG, which changed names over the years; today UHMWPE powder materials are produced by Ticona. UHMWPE is available commercially either as consolidated forms, such as sheets or rods, and as fibers. UHMWPE powder may also be directly molded into the final shape of a product. Because of its resistance to wear and impact, UHMWPE continues to find increasing industrial applications, including the automotive and bottling sectors, for example. Since the 1960s, UHMWPE has also been the material of choice for total joint arthoplasty in orthopedia and  spine implants. 

UHMWPE fibers, commercialised in the late 1970s by the Dutch chemicals company DSM, are widely used in ballistic protection, defense applications, and increasingly in medical devices as well.
Wikipedia: http://en.wikipedia.org/wiki/Dyneema (11/3/2008)

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Review Articles

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US Patents

12/30/2008

7,470,459
Ultra high molecular weight polyethylene ballistic structures

12/9/2008

 7,462,318
Crosslinked polymeric material with enhanced strength and process for manufacturing

12/2/2008

7,459,116
Method of manufacturing a ski

11/4/2008

7,445,735
Method of making microporous material

10/7/2008

7,431,874
Methods for making oxidation resistant polymeric material

9/30/2008

7,429,635
Preparation of ultra high molecular weight linear low density polyethylene

9/16/2008

7,425,357
Surface modification of expanded ultra high molecular weight polyethylene(eUHMWPE) for improved bondability

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Journal Articles

2/27/2009

Production of Ultrahigh-Molecular-Weight Polyethylene/Pristine MWCNT Composites by Half-Titanocene Catalysts 
(p 902-905)  
Advanced Materials 21 #8 (2009)
Abstract

Ultrahigh molecular weight polyethylene wear debris inhibits osteoprogenitor proliferation and differentiation in vitro 
(p 242-247)
 Journal of Biomedical Materials Research 89A #1 (2009)
Abstract

2/20/2009

Improved resistance to wear and fatigue fracture in high pressure crystallized vitamin E-containing ultra-high molecular weight polyethylene
(1870-1880) Biomaterials 30  #10 (2009)

2/6/2009

Effects of packaging environments on free radicals in gamma-irradiated UHMWPE resin powder blend with vitamin E 
(p 1097-1103)
Journal of Biomedical Materials Research 88A #4 (2009)
Abstract

1/23/2009

Design to Modify UHMWPE with Schiff Base Copper Complex for Use as Tribological Material
(7 – 19)  Journal of  Dispersion  Science and Technology 30 #1 (2009)

11/21/2008

PREPARATION OF MICROPOROUS ULTRA HIGH MOLECULAR WEIGHT POLYETHYLENE (UHMWPE) BY THERMALLY INDUCED PHASE SEPARATION OF A UHMWPE/LIQUID PARAFFIN MIXTURE
(653 – 657) Chinese Journal of Polymer Science 26, #6 (2008)

11/7/2008

Study on torsional fretting behavior of UHMWPE
(616-618) Applied Surface Science 255  #2 (2008)

10/31/1008

Morphology and mechanical properties of injection-molded ultrahigh molecular weight polyethylene/polypropylene blends and comparison with compression molding 
(p 890-898)
Journal of Applied Polymer  Science 111 #2 (2009)
Abstract

New and Simple Staining Method for Visualizing UHMWPE Lamellar Structure in TEM
(1148 – 1160) Journal of Macromolecular Science, Part B - Physics 47  #6 (2008)

9/26/2008

Investigation of the ultradrawing properties of gel spun fibers of ultra-high molecular weight polyethylene/carbon nanotube blends 
(p 2538-2548)
Journal of Applied Polymer  Science 110 #5 (2008)
Abstract

Yield, creep, and wear properties of ultra high molecular weight polyethylene processed by high velocity compaction 
(p 2579-2585)
Journal of Applied Polymer  Science 110 #5 (2008)
Abstract

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Roger D. Corneliussen
Editor
Telephone: 610 883 0055
rcorneliussen@4spe.org

www.maropolymeronline.com

Copyright 2008 by Roger D. Corneliussen